Services on Demand
Journal
Article
Indicators
- Cited by SciELO
- Access statistics
Related links
- Cited by Google
- Similars in SciELO
- Similars in Google
Share
Revista Facultad de Ingeniería Universidad de Antioquia
Print version ISSN 0120-6230On-line version ISSN 2422-2844
Abstract
VELASQUEZ, Carlos A. et al. Development of a flexible anode for lithium-ion batteries from electrospun carbon-magnetite composite microfibers. Rev.fac.ing.univ. Antioquia [online]. 2023, n.106, pp.94-102. Epub July 06, 2023. ISSN 0120-6230. https://doi.org/10.17533/udea.redin.20210319.
The development of a binder-free material is gaining ground as a flexible anode in lithium-ion batteries due to the higher specific capacity and possibilities of usage in portable appliances. In this work, magnetite nanoparticles (Fe3O4-NPs) were incorporated into carbon microfibers (CMFs) by electrospinning technique to improve the specific capacity of active material, retaining the high flexibility of the CMFs. The composite active material (CMFs-Fe3O4) was characterized by Raman spectroscopy, Thermogravimetric analyses (TGA), and transmission electron microscopy (TEM) to determine the composition, structure, and morphology of the composite. Electrochemical tests were done to evaluate the performance of the composite material as an anode in lithium-ion batteries. Fe3O4-NPs with particle sizes from 30 to 40 nm were incorporated into CMFs (800 nm), and the TEM images showed a homogeneous distribution of Fe3O4-NPs. The electrochemical tests evidenced that magnetite incorporation increases the specific capacity by 42% on the first cycle and 20% on the 50th cycle. Similarly, the Coulombic efficiency increases by 20% in the composite material.
Keywords : Electrochemistry; Energy conversión; Composite material; Carbon; Iron.