Abstract

CRUZ-ESTRADA, RICARDO HERBÉ; RIOS-SOBERANIS, CARLOS ROLANDO  and  CUPUL-MANZANO, CARLOS VIDAL. MELT-PROCESSING OF SBS/POLYANILINE-BASED BLENDS. Dyna rev.fac.nac.minas [online]. 2013, vol.80, n.178, pp.86-94. ISSN 0012-7353.

Morphological analysis and electrical conductivity of composites obtained by melt-processing of blends of a polyaniline complex (PANICX) with styrene-butadiene-styrene (SBS) are reported. Blends with PANICX contents ranging from 1 to 50 wt% were first prepared using a two-piece batch mixer, followed by ram-extrusion to obtain cord-like extrudates. The microstructure was analyzed by SEM, and conductivity was evaluated with a Keithley electrometer. The blends' rheological behavior was also studied. Evidence of formation of well-defined elongated structures was found in most of the extrudates. The extrudates' conductivity was considerably low. Inhomogeneity-related problems were observed such as erratic behavior of pressure, "melt-fracture" during the extrusion, and extrudates with irregular microstructure and very low conductivity. This occurred because same size batches were used regardless of blends' composition. As a result, the shearing occurring during compounding was not enough to disperse PANICX effectively within the SBS matrix.

Keywords : Conducting polymers; Polymer blends; Extrusion; Microstructure; Polymer processing.

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