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Ciencia en Desarrollo
versão impressa ISSN 0121-7488
Resumo
SALINAS, A. S; GUTIERREZ, J. V; LARMAT G, F. E e RAMIREZ-SANABRIA, A. E. Electrocatalytic Hydrogenation of Methyl Oleate and Methyl Linoleate by Titanium covered with by /Ni/SnO(x) type Systems. Ciencia en Desarrollo [online]. 2016, vol.7, n.1, pp.37-43. ISSN 0121-7488.
Abstract This paper presents the Electrocatalytic Hydrogenation (ECH) of methyl oleate and methyl linoleate results electrolysis potential by which active hydrogen is producedby cyclic voltametry, was established at −600 mV. The electrocatalysts used were based on Titaniumcovered with nickel systems supported over tin oxide (II) and (IV) showed different behavior towards the diverse substrata studied. Tin oxide (II) system was most active towards the methyl oleate hydrogenation, whereas, tin oxide (IV) system was most active to methyl linoleate hydrogenation.
Palavras-chave : Electrocatalysts; Electrocatalytic Hydrogenation; Methyl esters; Tin Oxides.